Electrolytic hydride generation (EC-HG) - a sample introduction system with some special features

被引:79
作者
Denkhaus, E [1 ]
Golloch, A
Guo, XM
Huang, B
机构
[1] Gerhard Mercator Univ Duisburg, Dept Instrumental Analyt Chem, Duisburg, Germany
[2] Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China
关键词
D O I
10.1039/b100185j
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Fundamental aspects of electrolytic hydride generation (EC-HG) and the application of EC-HG as a sample introduction system in atomic spectrometry are presented. One of the aims of this review is to help the analyst to select the most suitable electrolytic hydride generator and diverse operating parameters, and especially the choice of the cathode material, in relation to the requirements of the analytical problem. The application of EC-HG in speciation analysis of hydride-forming elements is one of the topics of this review. Additionally, the use of EC-HG is critically evaluated as an alternative to wet chemical hydride generation.
引用
收藏
页码:870 / 878
页数:9
相关论文
共 64 条
  • [31] Tubular electrolytic hydride generator for continuous and flow injection sample introduction in atomic absorption spectrometry
    Laborda, F
    Bolea, E
    Castillo, JR
    [J]. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2000, 15 (01) : 103 - 107
  • [32] The mechanism of electrolytic processes. Part III. Irreversible reductions.
    Leslie, WM
    Butler, JAV
    [J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1936, 32 (01): : 0989 - 0998
  • [33] LIN Y, 1991, THESIS XIAMEN U CHIN
  • [34] LIN Y, 1990, P 1990 CHANGCH INT S, P221
  • [35] LIN Y, 1989, P 3 BEIJ C EXH INSTR, pC119
  • [36] FLOW-INJECTION ELECTROCHEMICAL HYDRIDE GENERATION TECHNIQUE FOR ATOMIC-ABSORPTION SPECTROMETRY
    LIN, YH
    WANG, XR
    YUAN, DX
    YANG, PY
    HUANG, BL
    ZHUANG, ZX
    [J]. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1992, 7 (02) : 287 - 291
  • [37] Electrochemical and chemical processes for hydride generation in flow injection ICP-MS:: determination of arsenic in natural waters
    Machado, LFR
    Jacintho, AO
    Menegário, AA
    Zagatto, EAG
    Giné, MF
    [J]. JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1998, 13 (12) : 1343 - 1346
  • [38] Atomic spectrometric detection of hydride forming elements following in situ trapping within a graphite furnace
    Matusiewicz, H
    Sturgeon, RE
    [J]. SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1996, 51 (04) : 377 - 397
  • [39] Mizuike A., 1983, ENRICHMENT TECHNIQUE
  • [40] NARAYSZABO S, 1938, Z PHYS CHEM A LPZ, V181, P367