Effective catalysts for transfer hydrogenation of ketones and imines by propan-2-ol: Ruthenium-hydride or ruthenium-dihydride complexes

被引：45

作者：

Mizushima, E ^{[1
]}

Yamaguchi, M ^{[1
]}

Yamagishi, T ^{[1
]}

机构：

[1] TOKYO METROPOLITAN UNIV, FAC ENGN, DEPT IND CHEM, HACHIOJI, TOKYO 19203, JAPAN

来源：

CHEMISTRY LETTERS | 1997年 / 03期

关键词：

D O I：

10.1246/cl.1997.237

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The ruthenium-hydride complexes, [RuHCl(PPh3)(3)] and [RuH2(PPh3)(4)] act as very active catalyst for transfer hydrogenation of ketones and imines by propan-2-ol. The ruthenium-dihydride complex, [RuH2(PPh3)(4)], could catalyze the transfer hydrogenation without base.

引用

页码：237 / 238

页数：2

共 13 条

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