Growth and optical property of zinc oxide thornballs

被引:5
作者
Deng, GC [1 ]
Ding, AL [1 ]
Zheng, XS [1 ]
Cheng, WX [1 ]
Qiu, PS [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
关键词
nanostructures; crystal growth; luminescence; optical properties;
D O I
10.1016/j.materresbull.2005.03.012
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A new microstructure, thornball, of zinc oxide (ZnO) was synthesized by a very simple solid vapor deposition process under lead oxide (PbO) atmosphere. The microthornballs consist of numerous needles, which extend outwards in all directions symmetrically. They have dimensions of 120 mu m in diameter, while the average diameter of the needles is about 100-200 nm. The needles on the balls grow along the (0 0 0 1) orientation and have gradient compositions along radial. Control experiments proved that PbO played an important role in the growth. Additionally, photoluminescence property was observed and provided the evidence that PbO did not deteriorate the optical properties of ZnO thornballs. This kind of microstructures has potential applications in the field of photochemical catalysis. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:903 / 910
页数:8
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