Palladium-catalyzed benzylic C-H insertion of 2-substituted N-iminopyridinium ylides

被引：101

作者：

Mousseau, James J. ^{[1
]}

Larivee, Alexandre ^{[1
]}

Charette, Andre B. ^{[1
]}

机构：

[1] Univ Montreal, Dept Chem, Montreal, PQ H3C 3J7, Canada

来源：

ORGANIC LETTERS | 2008年 / 10卷 / 08期

关键词：

D O I：

10.1021/ol800396v

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed direct benzylic C-H arylation of 2-alkyl substituted N-iminopyridinium ylides is described. The insertion can be conducted with several electron-poor and electron-rich aryl chlorides in good yields. This work adds to the few examples of sp(3) C-H insertions that have been reported so far.

引用

页码：1641 / 1643

页数：3

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