New insights into the mechanism of phenolic oxidation with phenyliodonium(III) reagents

被引：75

作者：

Kürti, L

Herczegh, P

Visy, J

Simonyi, M

Antus, S

Pelter, A

机构：

[1] Lajos Kossuth Univ, Dept Organ Chem, H-4010 Debrecen, Hungary

[2] Hungarian Acad Sci, Antibiot Res Grp, H-4010 Debrecen, Hungary

[3] Hungarian Acad Sci, CRC, Inst Chem, H-1525 Budapest, Hungary

[4] Univ Wales, Dept Chem, Swansea SA2 8PP, W Glam, Wales

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1999年 / 04期

关键词：

D O I：

10.1039/a809206k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Calculations indicate that the position of oxidation of substituted phenols is in accord with the intervention of phenoxenium ions as intermediates, The lack of induction of chirality in the reaction whether using a preformed chiral iodonium reagent or a homochiral alcohol as;the medium also supports this hypothesis.

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收藏

页码：379 / 380

页数：2

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