Heteroleptic ruthenium antenna-dye for high-voltage dye-sensitized solar cells

被引：46

作者：

Li, Jheng-Ying ^{[1
]}

Chen, Chia-Yuan ^{[1
]}

Chen, Jian-Ging ^{[2
]}

Tan, Chun-Jui ^{[1
]}

Lee, Kun-Mu ^{[3
]}

Wu, Shi-Jhang ^{[1
]}

Tung, Yung-Liang ^{[3
]}

Tsai, Hui-Hsu ^{[1
]}

Ho, Kuo-Chuan ^{[2
]}

Wu, Chun-Guey ^{[1
]}

机构：

[1] Natl Cent Univ, Dept Chem, Jhongli 32001, Taiwan

[2] Natl Taiwan Univ, Dept Chem Engn, Taipei 10617, Taiwan

[3] Ind Technol Res Inst, Photovolta Technol Ctr, Hsinchu 31040, Taiwan

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2010年 / 20卷 / 34期

关键词：

CHARGE-TRANSFER SENSITIZERS; HIGH-EFFICIENCY; COUMARIN-DYE; PHOTOVOLTAIC PERFORMANCE; ENERGY CONVERSION; LIGHT; RECOMBINATION; ABSORPTIVITY; COMPLEXES; ENHANCE;

D O I：

10.1039/c0jm01418d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new ruthenium photosensitizer, coded CYC-B7, incorporating a bithienyl-carbazole antenna ligand was designed and prepared for improving the open-circuit voltage (V-oc) of a dye-sensitized solar cell (DSC) device. This new sensitizer displays the low energy MLCT transition band centered at 551 nm with a high molar absorption coefficient of 2.19 x 10(4) M-1 cm(-1). In addition, a simple approach to reduce the aggregation of bulky ruthenium dyes assembled onto the surface of TiO2 film is demonstrated. The cell based on this new heteroleptic ruthenium dye provides a high V-oc of 788 mV and an overall conversion efficiency (eta) of 8.96%. The functionality of carbazole in CYC-B7 resulting in the increases of the V-oc value of the corresponding device is verified by comparing with the performance of the DSC sensitized with a structurally similar dye without carbazole.

引用

收藏

页码：7158 / 7164

页数：7

相关论文

共 57 条

[1] Electron-rich heteroaromatic conjugated bipyridine based ruthenium sensitizer for efficient dye-sensitized solar cells [J].

Abbotto, Alessandro ;

Barolo, Claudia ;

Bellotto, Luca ;

De Angelis, Filippo ;

Graetzel, Michael ;

Manfredi, Norberto ;

Marinzi, Chiara ;

Fantacci, Simona ;

Yum, Jun-Ho ;

Nazeeruddin, Mohammad K. .

CHEMICAL COMMUNICATIONS, 2008, (42) :5318-5320

[2] Synthesis, characterization, and DFT-TDDFT computational study of a ruthenium complex containing a functionalized tetradentate ligand [J].

Barolo, C. ;

Nazeeruddin, Md. K. ;

Fantacci, Simona ;

Di Censo, D. ;

Comte, P. ;

Liska, P. ;

Viscardi, G. ;

Quagliotto, P. ;

De Angelis, Filippo ;

Ito, S. ;

Graetzel, M. .

INORGANIC CHEMISTRY, 2006, 45 (12) :4642-4653

[3] Quantum calculation of molecular energies and energy gradients in solution by a conductor solvent model [J].

Barone, V ;

Cossi, M .

JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (11) :1995-2001

[4] Dye-Sensitized Solar Cells with a High Absorptivity Ruthenium Sensitizer Featuring a 2-(Hexylthio)thiophene Conjugated Bipyridine [J].

Cao, Yiming ;

Bai, Yu ;

Yu, Qingjiang ;

Cheng, Yueming ;

Liu, Shi ;

Shi, Dong ;

Gao, Feifei ;

Wang, Peng .

JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (15) :6290-6297

[5]

Chen C.Y., 2008, ANGEW CHEM, V120, P7452

[6] Multifunctionalized ruthenium-based supersensitizers for highly efficient dye-sensitized solar cells [J].

Chen, Chia-Yuan ;

Chen, Jian-Ging ;

Wu, Shi-Jhang ;

Li, Jheng-Ying ;

Wu, Chun-Guey ;

Ho, Kuo-Chuan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (38) :7342-7345

[7] A new route to enhance the light-harvesting capability of ruthenium complexes for dye-sensitized solar cells [J].

Chen, Chia-Yuan ;

Wu, Shi-Jhang ;

Li, Jheng-Ying ;

Wu, Chun-Guey ;

Chen, Jian-Ging ;

Ho, Kuo-Chuan .

ADVANCED MATERIALS, 2007, 19 (22) :3888-+

[8] New ruthenium complexes containing oligoalkylthiophene-substituted 1,10-phenanthroline for nanocrystalline dye-sensitized solar cells [J].

Chen, Chia-Yuan ;

Lu, Hung-Chieh ;

Wu, Chun-Guey ;

Chen, Jian-Ging ;

Ho, Kuo-Chuan .

ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (01) :29-36

[9] A ruthenium complex with superhigh light-harvesting capacity for dye-sensitized solar cells [J].

Chen, Chia-Yuan ;

Wu, Shi-Jhang ;

Wu, Chun-Guey ;

Chen, Jian-Ging ;

Ho, Kuo-Chuan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (35) :5822-5825

[10] Highly Efficient Light-Harvesting Ruthenium Sensitizer for Thin-Film Dye-Sensitized Solar Cells [J].

Chen, Chia-Yuan ;

Wang, Mingkui ;

Li, Jheng-Ying ;

Pootrakulchote, Nuttapol ;

Alibabaei, Leila ;

Ngoc-le, Cevey-ha ;

Decoppet, Jean-David ;

Tsai, Jia-Hung ;

Graetzel, Carole ;

Wu, Chun-Guey ;

Zakeeruddin, Shaik M. ;

Graetzel, Michael .

ACS NANO, 2009, 3 (10) :3103-3109

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