A new route to enhance the light-harvesting capability of ruthenium complexes for dye-sensitized solar cells

被引:162
作者
Chen, Chia-Yuan
Wu, Shi-Jhang
Li, Jheng-Ying
Wu, Chun-Guey [1 ]
Chen, Jian-Ging
Ho, Kuo-Chuan
机构
[1] Natl Cent Univ, Dept Chem, Jhongli 32001, Taiwan
[2] Natl Taiwan Univ, Dept Chem Engn, Taipei 10617, Taiwan
关键词
D O I
10.1002/adma.200701111
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two new heteroleptic ruthenium-based dyes, SJW-El and CYC-B3 (see figure), with very high photon-to-current conversion efficiency are reported and their application in dye-sensitized solar cells (DSCs) described. The higher performance of SJW-E1 in DSCs is suggested to arise from successful molecular-engineering of the ancillary ligand, that is, two-dimensional conjugation enhancement and functional group substitution.
引用
收藏
页码:3888 / +
页数:5
相关论文
共 15 条
[1]   Determination of parameters of electron transport in dye-sensitized solar cells using electrochemical impedance spectroscopy [J].
Adachi, Motonari ;
Sakamoto, Masaru ;
Jiu, Jinting ;
Ogata, Yukio ;
Isoda, Seiji .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (28) :13872-13880
[2]   New ruthenium complexes containing oligoalkylthiophene-substituted 1,10-phenanthroline for nanocrystalline dye-sensitized solar cells [J].
Chen, Chia-Yuan ;
Lu, Hung-Chieh ;
Wu, Chun-Guey ;
Chen, Jian-Ging ;
Ho, Kuo-Chuan .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (01) :29-36
[3]   A ruthenium complex with superhigh light-harvesting capacity for dye-sensitized solar cells [J].
Chen, Chia-Yuan ;
Wu, Shi-Jhang ;
Wu, Chun-Guey ;
Chen, Jian-Ging ;
Ho, Kuo-Chuan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (35) :5822-5825
[4]   Modification of electron transfer properties in photoelectrochemical solar cells by substituting {Ru(terpy)2}2+ dyes with thiophene [J].
Figgemeier, E ;
Aranyos, V ;
Constable, EC ;
Handel, RW ;
Housecroft, CE ;
Risinger, C ;
Hagfeldt, A ;
Mukhtar, E .
INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (01) :117-121
[5]   Photovoltaic characterization of dye-sensitized solar cells:: Effect of device masking on conversion efficiency [J].
Ito, Seigo ;
Nazeeruddin, Md. Khaja ;
Liska, Paul ;
Comte, Pascal ;
Charvet, Raphael ;
Pechy, Peter ;
Jirousek, Marie ;
Kay, Andreas ;
Zakeeruddin, Shaik M. ;
Graetzel, Michael .
PROGRESS IN PHOTOVOLTAICS, 2006, 14 (07) :589-601
[6]   Oligophenylenevinylene-functionalized Ru(II)-bipyridine sensitizers for efficient dye-sensitized nanocrystalline TiO2 solar cells [J].
Jang, Song-Rim ;
Lee, Chongchan ;
Choi, Hyunbong ;
Ko, Jae Jung ;
Lee, Jiwon ;
Vittal, R. ;
Kim, Kang-Jin .
CHEMISTRY OF MATERIALS, 2006, 18 (23) :5604-5608
[7]   A novel ruthenium sensitizer with a hydrophobic 2-thiophen-2-yl-vinyl-conjugated bipyridyl ligand for effective dye sensitized TiO2 solar cells [J].
Jiang, Ke-Jian ;
Masaki, Naruhiko ;
Xia, Jiang-Bin ;
Noda, Shuji ;
Yanagida, Shozo .
CHEMICAL COMMUNICATIONS, 2006, (23) :2460-2462
[8]   High molar extinction coefficient ion-coordinating ruthenium sensitizer for efficient and stable mesoscopic dye-sensitized solar cells [J].
Kuang, Daibin ;
Klein, Cedric ;
Ito, Seigo ;
Moser, Jacques-E. ;
Humphry-Baker, Robin ;
Zakeeruddin, Shaik. M. ;
Graetzel, Michael .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (01) :154-160
[9]   High molar extinction coefficient heteroleptic ruthenium complexes for thin film dye-sensitized solar cells [J].
Kuang, DB ;
Ito, S ;
Wenger, B ;
Klein, C ;
Moser, JE ;
Humphry-Baker, R ;
Zakeeruddin, SM ;
Grätzel, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (12) :4146-4154
[10]   Combined experimental and DFT-TDDFT computational study of photoelectrochemical cell ruthenium sensitizers [J].
Nazeeruddin, MK ;
De Angelis, F ;
Fantacci, S ;
Selloni, A ;
Viscardi, G ;
Liska, P ;
Ito, S ;
Bessho, T ;
Grätzel, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (48) :16835-16847