Ionic liquids as reaction media for polymerization processes: atom transfer radical polymerization (ATRP) of acrylates in ionic liquids

被引：79

作者：

Biedron, T ^{[1
]}

Kubisa, P ^{[1
]}

机构：

[1] Polish Acad Sci, Ctr Mol & Macromol Studies, PL-90363 Lodz, Poland

来源：

POLYMER INTERNATIONAL | 2003年 / 52卷 / 10期

关键词：

atoms transfer radical polymerization (ATRP); ionic liquids; chiral ionic liquids; polyacrylates;

D O I：

10.1002/pi.1343

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Application of ionic liquids (organic salts that are liquid at ambient temperatures) as solvents for atom transfer radical polymerization (ATRP) of acrylic monomers is described. Ionic liquids dissolve several inorganic and organic compounds, are highly polar and non-volatile. It has been shown that their application as solvents in ATRP of acrylates allows the reduction of side-reactions when compared against bulk polymerizations. When chiral ionic liquid was used as a solvent a small but clear effect on polymer tacticity was observed. (C) 2003 Society of Chemical Industry.

引用

页码：1584 / 1588

页数：5

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