Isolation of [Sn(PSe5)3](5-) and [Sn2Se4(PSe5)(2)](6-); The first discrete complexes from molten alkali-metal polyselenophosphate fluxes

被引：17

作者：

Chondroudis, K ^{[1
]}

Kanatzidis, MG ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,DEPT CHEM,E LANSING,MI 48824

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 11期

关键词：

D O I：

10.1039/cc9960001371

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of basic polychalcophosphate fluxes yields the quaternary molecular compounds [Sn(PSe5)(3)](5-) and [Sn2Se4(PSe5)(2)](6-), the first examples of discrete complexes produced from molten fluxes.

引用

页码：1371 / 1372

页数：2

共 10 条

[1] COMPLEX MULTINARY COMPOUNDS FROM MOLTEN ALKALI-METAL POLYSELENOPHOSPHATE FLUXES - LAYERS AND CHAINS IN A(4)TI(2)(P2SE9)(2)(P2SE7) AND ATIPSE(5) (A=K, RB) - ISOLATION OF [P2SE9](4-), A FLUX CONSTITUENT ANION [J].

CHONDROUDIS, K ;

KANATZIDIS, MG .

INORGANIC CHEMISTRY, 1995, 34 (22) :5401-&

[2]

CHONDROUDIS K, 1996, INORG CHEM, V35, P841

[3] SYNTHESIS, STRUCTURE AND SE-77/SN-119 NMR-SPECTROSCOPY OF THE NEW POLYSELENIDE, TRIS(TETRASELENIDO)STANNATE(IV), [SN(SE4)3]2- [J].

HUANG, SP ;

DHINGRA, S ;

KANATZIDIS, MG .

POLYHEDRON, 1990, 9 (11) :1389-1395

[4] COORDINATION CHEMISTRY OF [P2SE6](4-) IN MOLTEN FLUXES - ISOLATION OF THE STRUCTURALLY COMPLEX KMP(2)SE(6) (M=SB, BI) [J].

MCCARTHY, TJ ;

KANATZIDIS, MG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (09) :1089-1090

[5] USE OF MOLTEN ALKALI-METAL POLYTHIOPHOSPHATE FLUXES FOR SYNTHESIS AT INTERMEDIATE TEMPERATURES - ISOLATION AND STRUCTURAL CHARACTERIZATION OF ABIP2S7 (A = K, RB) [J].

MCCARTHY, TJ ;

KANATZIDIS, MG .

CHEMISTRY OF MATERIALS, 1993, 5 (08) :1061-1063

[6] SYNTHESIS IN MOLTEN ALKALI-METAL POLYSELENOPHOSPHATE FLUXES - A NEW FAMILY OF TRANSITION-METAL SELENOPHOSPHATE COMPOUNDS, A(2)MP(2)SE(6) (A=K, RB, CS, M=MN, FE) AND A(2)M'2P2SE6 (A=K, CS M'=CU, AG) [J].

MCCARTHY, TJ ;

KANATZIDIS, MG .

INORGANIC CHEMISTRY, 1995, 34 (05) :1257-1267

[7] SB...SB AND BI...BI INTERACTIONS IN CS8M4(P2SE6)5 (M=SB, BI) [J].

MCCARTHY, TJ ;

HOGAN, T ;

KANNEWURF, CR ;

KANATZIDIS, MG .

CHEMISTRY OF MATERIALS, 1994, 6 (07) :1072-1079

[8] MONOMERIC SELENOPALLADATES AND SELENOPLATINATES [J].

MCCONNACHIE, JM ;

ANSARI, MA ;

IBERS, JA .

INORGANIC CHEMISTRY, 1993, 32 (15) :3250-3255

[9] PREPARATION AND CRYSTAL-STRUCTURE OF CS4SN2SE6 [J].

SHELDRICK, WS ;

BRAUNBECK, HG .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1989, 44 (07) :851-852

[10] CHEMISTRY OF PHOSPHORUS SELENIDE ANIONS - SYNTHESIS AND STRUCTURE OF P2SE82- AND [FE2(CO)4(PSE5)2]2- [J].

ZHAO, J ;

PENNINGTON, WT ;

KOLIS, JW .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (03) :265-266

← 1 →