CHEMISTRY OF PHOSPHORUS SELENIDE ANIONS - SYNTHESIS AND STRUCTURE OF P2SE82- AND [FE2(CO)4(PSE5)2]2-

被引：34

作者：

ZHAO, J ^{[1
]}

PENNINGTON, WT ^{[1
]}

KOLIS, JW ^{[1
]}

机构：

[1] CLEMSON UNIV,DEPT CHEM,CLEMSON,SC 29634

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 03期

关键词：

D O I：

10.1039/c39920000265

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction Of P4Se4 with soluble polyselenides generates the first isolated phosphorus selenide anion, P2Se82-, which further reacts with an excess of Fe(CO)5 to generate the novel cluster [Fe2(CO)4(PSe5)2]2-, which has been characterized by crystallography.

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页码：265 / 266

页数：2

相关论文

共 12 条

[1] A NOVEL PHOSPHORUS CHALCOGENIDE - P2SE5 [J].

BLACHNIK, R ;

BALDUS, HP ;

LONNECKE, P ;

TATTERSHALL, BW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (05) :605-607

[2] STEREOCHEMICAL ANALYSIS OF FE2(CO)6(MU-SE2) - DISELENIUM ANALOG OF FE2(CO)6(MU-S2) [J].

CAMPANA, CF ;

LO, FYK ;

DAHL, LF .

INORGANIC CHEMISTRY, 1979, 18 (11) :3060-3064

[3]

CORBRIDGE DEC, 1990, PHOSPHORUS OUTLINE I

[4] (NH4)4[P4S8].2H2O, THE SALT OF A SQUARE PHOSPHORIC-ACID [J].

FALIUS, H ;

KRAUSE, W ;

SHELDRICK, WS .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1981, 20 (01) :103-104

[5] THE PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF (PME)4SE3 [J].

HALL, SW ;

PILKINGTON, MJ ;

SLAWIN, AMZ ;

WILLIAMS, DJ ;

WOOLLINS, JD .

POLYHEDRON, 1991, 10 (02) :261-265

[6]

Hoffmann H., 1976, TOPICS PHOSPHORUS CH, V8, P193

[7] COORDINATION CHEMISTRY OF POLYCHALCOGEN ANIONS AND TRANSITION-METAL CARBONYLS [J].

KOLIS, JW .

COORDINATION CHEMISTRY REVIEWS, 1990, 105 :195-219

[8]

MISHALL PC, 1978, ACTA CRYSTALLOGR B, V34, P1378

[9] PREPARATION AND STRUCTURE OF [SE=W(PSE4)(PSE2)]2- - A CLUSTER CONTAINING A HETEROALLYLIC PSE2- UNIT [J].

ONEAL, SC ;

PENNINGTON, WT ;

KOLIS, JW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (12) :1486-1488

[10] NOVEL TRANSITION-METAL MAIN-GROUP HYBRID CAGES - SYNTHESIS AND CHARACTERIZATION OF [MOAS2SE10]2- AND [W2AS2SE13]2- [J].

ONEAL, SC ;

PENNINGTON, WT ;

KOLIS, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (02) :710-712