Evidence for the pathway of metal triangle rotation in solid M(3)(CO)(12): Variable-temperature X-ray structures of Fe2Ru(CO)(12) and FeRu2(CO)(12)

被引：20

作者：

Braga, D ^{[1
]}

Farrugia, L ^{[1
]}

Gillon, AL ^{[1
]}

Grepioni, F ^{[1
]}

Tedesco, E ^{[1
]}

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 22期

关键词：

D O I：

10.1021/om960512f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fe2Ru(CO)(12) has the Fe-3(CO)(12) structure, while FeRu2(CO)(12) has an all-terminal D-3 structure: the metal disorder in FeRu2(CO)(12) at high temperatures provides direct evidence for the pathway of metal triangle rotation in the solid state.

引用

页码：4684 / 4686

页数：3

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