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A carbene-stabilized gold(I) fluoride:: Synthesis and theory

被引：120
作者：
Laitar, DS
Müller, P
Gray, TG
Sadighi, JP
机构：
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
[2] Case Western Reserve Univ, Cleveland, OH 44106 USA
来源：
ORGANOMETALLICS | 2005年 / 24卷 / 19期
关键词：
D O I：
10.1021/om050619f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first isolable gold(I) fluoride complex, stabilized by an N-heterocyclic carbene (NHC) ligand, has been isolated in two-coordinate monomeric form. DFT calculations show significant p pi/d pi interactions between fluoride and gold(I) and indicate a substantial negative charge on fluorine.
引用
收藏
页码：4503 / 4505
页数：3
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