Exploring the ruthenium catalysed synthesis of γ-valerolactone in alcohols and utilisation of mild solvent-free reaction conditions

被引：257

作者：

Al-Shaal, Mohammad G. ^{[1
]}

Wright, William R. H. ^{[1
]}

Palkovits, Regina ^{[1
]}

机构：

[1] Univ Aachen, RWTH, Inst Tech & Makromol Chem, D-52074 Aachen, Germany

来源：

GREEN CHEMISTRY | 2012年 / 14卷 / 05期

关键词：

LEVULINIC ACID; ETHYL LEVULINATE; BIOMASS; CONVERSION; LIQUID; HYDROGEN; PLATFORM; BIOFUELS;

D O I：

10.1039/c2gc16631c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Levulinic acid and alkyl-levulinates have been hydrogenated using a range of supported catalysts. The different reaction outcomes obtained in alternate solvents have been rationalized and the influence of varying catalyst supports examined. A range of solvent free conditions have been investigated with complete LA conversion obtained at temperatures as low as 25 degrees C.

引用

页码：1260 / 1263

页数：4

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