Liquid-phase catalytic transfer hydrogenation and cyclization of levulinic acid and its esters to γ-valerolactone over metal oxide catalysts

被引:405
作者
Chia, Mei [1 ]
Dumesic, James A. [1 ]
机构
[1] Univ Wisconsin, Dept Chem & Biol Engn, Madison, WI 53706 USA
基金
美国国家科学基金会;
关键词
PONNDORF-VERLEY REDUCTION; HETEROGENEOUS CATALYSTS; RANEY-NICKEL; FORMIC-ACID; CONVERSION; ALCOHOLS; ACETONE; FUELS; ZRO2;
D O I
10.1039/c1cc14748j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Levulinic acid and its esters are converted to gamma-valerolactone over metal oxide catalysts by catalytic transfer hydrogenation via the Meerwein-Ponndorf-Verley reaction.
引用
收藏
页码:12233 / 12235
页数:3
相关论文
共 26 条
[1]   Production of Biofuels from Cellulose and Corn Stover Using Alkylphenol Solvents [J].
Alonso, David Martin ;
Wettstein, Stephanie G. ;
Bond, Jesse Q. ;
Root, Thatcher W. ;
Dumesic, James A. .
CHEMSUSCHEM, 2011, 4 (08) :1078-1081
[2]   Integrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels [J].
Bond, Jesse Q. ;
Alonso, David Martin ;
Wang, Dong ;
West, Ryan M. ;
Dumesic, James A. .
SCIENCE, 2010, 327 (5969) :1110-1114
[3]   Production of liquid hydrocarbon fuels by catalytic conversion of biomass-derived levulinic acid [J].
Braden, Drew J. ;
Henao, Carlos A. ;
Heltzel, Jacob ;
Maravelias, Christos T. ;
Dumesic, James A. .
GREEN CHEMISTRY, 2011, 13 (07) :1755-1765
[4]   Kinetic studies of ketone hydrogenation over Raney nickel catalyst [J].
Chang, NS ;
Aldrett, S ;
Holtzapple, MT ;
Davison, RR .
CHEMICAL ENGINEERING SCIENCE, 2000, 55 (23) :5721-5732
[5]   Meerwein-Ponndorf-Verley reduction over heterogeneous catalysts [J].
Chuah, G. K. ;
Jaenicke, S. ;
Zhu, Y. Z. ;
Liu, S. H. .
CURRENT ORGANIC CHEMISTRY, 2006, 10 (13) :1639-1654
[6]   The mechanism of aluminum-catalyzed Meerwein-Schmidt-Ponndorf-Verley reduction of carbonyls to alcohols [J].
Cohen, R ;
Graves, CR ;
Nguyen, SBT ;
Martin, JML ;
Ratner, MA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (45) :14796-14803
[7]   Conversion of Levulinic Acid and Formic Acid into γ-Valerolactone over Heterogeneous Catalysts [J].
Deng, Li ;
Zhao, Yan ;
Li, Jiang ;
Fu, Yao ;
Liao, Bing ;
Guo, Qing-Xiang .
CHEMSUSCHEM, 2010, 3 (10) :1172-1175
[8]   Catalytic Conversion of Biomass-Derived Carbohydrates into γ-Valerolactone without Using an External H2 Supply [J].
Deng, Li ;
Li, Jiang ;
Lai, Da-Ming ;
Fu, Yao ;
Guo, Qing-Xiang .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (35) :6529-6532
[9]  
Fitzpatrick S.W., 2005, The Biofine Technology: A "Bio-refinery" Concept Based on Thermochemical Conversion of Cellulosic Biomass
[10]   THE NATURE OF RANEY-NICKEL, ITS ADSORBED HYDROGEN AND ITS CATALYTIC ACTIVITY FOR HYDROGENATION REACTIONS - REVIEW [J].
FOUILLOUX, P .
APPLIED CATALYSIS, 1983, 8 (01) :1-42