Catalytic Conversion of Biomass-Derived Carbohydrates into γ-Valerolactone without Using an External H2 Supply

被引：337

作者：

Deng, Li ^{[1
]}

Li, Jiang ^{[1
]}

Lai, Da-Ming ^{[1
]}

Fu, Yao ^{[1
]}

Guo, Qing-Xiang ^{[1
]}

机构：

[1] Univ Sci & Technol China, Anhui Prov Key Lab Biomass Clean Energy, Dept Chem, Hefei 230026, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 35期

关键词：

formic acid; levulinic acid; sustainable chemistry; gamma-valerolactone; LIGNOCELLULOSIC BIOMASS; LIQUID FUELS; CHEMICALS; ALKANES; ACID; TRANSFORMATION; HYDROGEN;

D O I：

10.1002/anie.200902281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Simplified procedure: A new catalytic route was developed for the conversion of biomass carbohydrates into γ-valerolactone (GVL) without using an external H2 supply. A model experiment with glucose provided γ- valerolactone in 48 % yield. An interesting positive effect of CO 2 on the Ru-catalyzed hydrogenation was also observed. py=pyridine. © 2009 Wiley-VCH Verlag GmbH & Co. KCaA.

引用

页码：6529 / 6532

页数：4

共 28 条

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[Anonymous], 2008, ANGEW CHEM-GER EDIT

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