Synthesis and x-ray crystal structure of a chlorobis(trimethylsiloxy)zirconium silyl derivative, (Me3SiO)2Zr(SiPh2But)Cl•2THF

被引：34

作者：

Wu, ZZ ^{[1
]}

Diminnie, JB ^{[1
]}

Xue, ZL ^{[1
]}

机构：

[1] Univ Tennessee, Dept Chem, Knoxville, TN 37996 USA

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 13期

关键词：

D O I：

10.1021/om980148f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chlorobis(trimethylsiloxy)zirconium silyl derivative (Me3SiO)(2)Zr(SiPh2But)Cl . 2THF (2) and its precursor (Me3SiO)(2)ZrCl2. 2THF (1) have been synthesized and characterized by X-ray crystallography. The Zr-Si bond distance of 2.848(3) Angstrom in 2 is, to our knowledge, the longest reported Zr-Si bond to date.

引用

页码：2917 / 2920

页数：4

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