Glass transition measurements on heterogeneous surfaces

被引：16

作者：

Dinelli, F ^{[1
]}

Buenviaje, C ^{[1
]}

Overney, RM ^{[1
]}

机构：

[1] Univ Washington, Dept Chem Engn, Seattle, WA 98195 USA

来源：

THIN SOLID FILMS | 2001年 / 396卷 / 1-2期

关键词：

atomic force microscopy (AFM); scanning force microscopy (SFM); glass transition temperature (T-g); polymers; surface analysis; calorimetry; tribology; nanorheology; blends; emulsions;

D O I：

10.1016/S0040-6090(01)01190-7

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The local glass transition temperature (T-g) of heterogeneous polymer surfaces has been successfully determined by lateral force microscopy (LFM) on the submicron-nanometer scale. This paper addresses interfacial confinement effects in thin films of blends and emulsions from polystyrene (PS), poly(butylmethacrylate) (PBMA) and poly(methylmethacrylate) (PMMA). The paper addresses the difficulty of thermal rheological experiments with a microscopic scanning technique, and introduces an in-situ calibration method. (C) 2001 Elsevier Science B.V. All rights reserved.

引用

页码：138 / 144

页数：7

共 18 条

[11]

MARTI O, 1999, ACS SYM SER, V741, P212

[12] Excitation of surface deformation modes of a phase-separating polymer blend on a patterned substrate [J].

Nisato, G ;

Ermi, BD ;

Douglas, JF ;

Karim, A .

MACROMOLECULES, 1999, 32 (07) :2356-2364

[13]

OVERNEY R, 1998, ACS SYM SER, V694, P2

[14] Glass and structural transitions measured at polymer surfaces on the nanoscale [J].

Overney, RM ;

Buenviaje, C ;

Luginbühl, R ;

Dinelli, F .

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2000, 59 (1-2) :205-225

[15] Dimensional crossover in the phase separation kinetics of thin polymer blend films [J].

Sung, L ;

Karim, A ;

Douglas, JF ;

Han, CC .

PHYSICAL REVIEW LETTERS, 1996, 76 (23) :4368-4371

[16] Film thickness dependence of the surface structure of immiscible polystyrene/poly(methyl methacrylate) blends [J].

Tanaka, K ;

Takahara, A ;

Kajiyama, T .

MACROMOLECULES, 1996, 29 (09) :3232-3239

[17] Studying surface glass-to-rubber transition using atomic force microscopic adhesion measurements [J].

Tsui, OKC ;

Wang, XP ;

Ho, JYL ;

Ng, TK ;

Xiao, XD .

MACROMOLECULES, 2000, 33 (11) :4198-4204

[18] Structure formation via polymer demixing in spin-cast films [J].

Walheim, S ;

Boltau, M ;

Mlynek, J ;

Krausch, G ;

Steiner, U .

MACROMOLECULES, 1997, 30 (17) :4995-5003

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