INFLUENCE OF pH VALUE ON THE STRUCTURES AND OPTICAL PROPERTIES OF ZnO NANOCRYSTALLINE SYNTHESIZED WITH A SOLUTION PROCESS

被引:13
作者
He, Guan-Nan [1 ,2 ]
Wu, Sun-Tao [1 ]
Li, Jing [1 ]
Huang, Bo [3 ]
Wu, Qi-Hui [4 ]
机构
[1] Xiamen Univ, Pen Tung Sah Micronano Technol Res Ctr, Xiamen 361005, Peoples R China
[2] Zhongshan Univ, Dept Phys, Guangzhou 510275, Peoples R China
[3] Jinan Univ, Dept Elect Engn, Guangzhou 510632, Peoples R China
[4] La Trobe Univ, Dept Phys, Bundoora, Vic 3086, Australia
关键词
ZnO; nanomaterials; solution process; GROWTH; NANOSTRUCTURES; LUMINESCENCE; NANORODS;
D O I
10.1142/S1793604710001044
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Three types of hexagonal wurtzite ZnO nanostructures namely nanorods, nanodisks and nanoflowers were prepared in three different pH value solutions. The results indicated that the concentration of H+ ions in the solution would greatly affect the growth behaviors of ZnO crystal. In addition to a broad ultraviolet emission found on the photoluminescence spectra, two weaker peaks corresponding to the blue emission of ZnO were observed at 2.75 and 2.68eV, which probably originate from the electron transition from the shallow donor level of interstitial Zn to the valence band of ZnO.
引用
收藏
页码:107 / 110
页数:4
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