Anthracene derivatives bearing two urea groups as fluorescent receptors for anions

被引:94
作者
Kim, SK
Singh, NJ
Kim, SJ
Swamy, KMK
Kim, SH
Lee, KH
Kim, KS
Yoon, J
机构
[1] Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea
[2] Ewha Womans Univ, Div Nanosci, Seoul 120750, South Korea
[3] Pohang Univ Sci & Technol, Natl Creat Res Initiat Ctr Superfunct Mat, Dept Chem, Div Mol & Life Sci, Pohang 790784, South Korea
[4] Inha Univ, Dept Chem, Inchon 402751, South Korea
关键词
fluorescence; fluorescence chemosensor; anion; anion-receptor; pyrophosphate; adipate; dicarboxylates; molecular recognition;
D O I
10.1016/j.tet.2005.03.009
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
For the recognition and sensing of anionic analytes, comparative studies were carried out on the anion bindings of pyrophosphate, H2PO4-, and dicarboxylates to the anthracene derivatives bearing two urea groups on the 1,8 and 9, 10-positions as fluorescent chemosensors for anions. Their binding properties were compared using fluorescence and H-1 NMR, and the results were rationalized with an ab initio study. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4545 / 4550
页数:6
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