Coordination polymers of flexible tetracarboxylic acids with metal ions. I. Synthesis of CH2- and (CH2)2-spaced bis(oxy)isophthalic acid ligands, and structural characterization of their polymeric adducts with lanthanoid ions

被引：61

作者：

Karmakar, Anirban ^{[1
]}

Goldberg, Israel ^{[1
]}

机构：

[1] Tel Aviv Univ, Sackler Fac Exact Sci, Sch Chem, IL-69978 Tel Aviv, Israel

来源：

CRYSTENGCOMM | 2011年 / 13卷 / 01期

基金：

以色列科学基金会;

关键词：

SECONDARY BUILDING UNITS; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; MICROPOROUS METAL; 1,2,4,5-BENZENETETRACARBOXYLIC ACID; SOLVOTHERMAL SYNTHESIS; HYDROTHERMAL SYNTHESIS; LUMINESCENT PROPERTIES; SILVER(I) COMPLEXES; THERMAL-STABILITY;

D O I：

10.1039/c0ce00474j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report herein on the synthesis and structure of new tetracarboxylic ligands, 5,5'-methylene-bis(oxy)diisophthalic acid and 5,5'-(ethane-1,2-diyl)-bis(oxy) diisophthalic acid, bearing flexible spacers between the two isophthalic acid fragments, as well as of the coordination polymers of these two ligands with various lanthanoid metal ions. The formed compounds were characterized by X-ray crystallography, IR spectroscopy and thermal analysis. The nine hybrid organic-inorganic supramolecular assemblies reveal polymeric architectures of either two-dimensional or three-dimensional connectivity.

引用

页码：339 / 349

页数：11

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