Investigation of thermal and electrical conductivity of graphene based nanofluids

被引:220
作者
Baby, Tessy Theres [1 ]
Ramaprabhua, S. [1 ]
机构
[1] Indian Inst Technol Madras, NFMTC, AENL, Dept Phys, Madras 600036, Tamil Nadu, India
关键词
MULTIWALLED CARBON NANOTUBES; SHEETS; OXIDE;
D O I
10.1063/1.3516289
中图分类号
O59 [应用物理学];
学科分类号
070305 [高分子化学与物理];
摘要
We report for the first time, the synthesis of highly stable exfoliated graphene based nanofluids with water and ethylene glycol as base fluids with out any surfactant and the subsequent studies on their thermal and electrical conductivities. Graphene was synthesized by thermal exfoliation of graphene oxide at 1050 degrees C in Ar atmosphere. The as-synthesized graphene has been suitably functionalized and further dispersed it in the base fluids without any surfactant. Thermal and electrical conductivities of these nanofluids were measured for varying volume fractions and at different temperatures. An enhancement in thermal conductivity by about 14% has been achieved at 25 degrees C with deionized water (DI) as base fluid at a very low volume fraction of 0.056% which increases to about 64% at 50 degrees C. Electrical conductivity measurements for these nanofluids indicate an enormous enhancement at 25 degrees C for a volume fraction of 0.03% in DI water. (C) 2010 American Institute of Physics. [doi:10.1063/1.3516289]
引用
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页数:6
相关论文
共 26 条
[1]
High-Throughput Synthesis of Graphene by Intercalation - Exfoliation of Graphite Oxide and Study of Ionic Screening in Graphene Transistor [J].
Ang, Priscilla Kailian ;
Wang, Shuai ;
Bao, Qiaoliang ;
Thong, John T. L. ;
Loh, Kian Ping .
ACS NANO, 2009, 3 (11) :3587-3594
[2]
Thermal conductivity of nanofluids - Experimental and theoretical [J].
Assael, M. J. ;
Metaxa, I. N. ;
Kakosimos, K. ;
Constantinou, D. .
INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2006, 27 (04) :999-1017
[3]
Superior thermal conductivity of single-layer graphene [J].
Balandin, Alexander A. ;
Ghosh, Suchismita ;
Bao, Wenzhong ;
Calizo, Irene ;
Teweldebrhan, Desalegne ;
Miao, Feng ;
Lau, Chun Ning .
NANO LETTERS, 2008, 8 (03) :902-907
[4]
Anomalous thermal conductivity enhancement in nanotube suspensions [J].
Choi, SUS ;
Zhang, ZG ;
Yu, W ;
Lockwood, FE ;
Grulke, EA .
APPLIED PHYSICS LETTERS, 2001, 79 (14) :2252-2254
[5]
Anomalously increased effective thermal conductivities of ethylene glycol-based nanofluids containing copper nanoparticles [J].
Eastman, JA ;
Choi, SUS ;
Li, S ;
Yu, W ;
Thompson, LJ .
APPLIED PHYSICS LETTERS, 2001, 78 (06) :718-720
[6]
THERMAL CONDUCTIVITY OF HETEROGENEOUS 2-COMPONENT SYSTEMS [J].
HAMILTON, RL ;
CROSSER, OK .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1962, 1 (03) :187-&
[7]
PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[8]
Synthesis and thermal conductivity of copper nanoparticle decorated multiwalled carbon nanotubes based nanofluids [J].
Jha, Neetu ;
Ramaprabhu, S. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (25) :9315-9319
[9]
Raman spectra of graphite oxide and functionalized graphene sheets [J].
Kudin, Konstantin N. ;
Ozbas, Bulent ;
Schniepp, Hannes C. ;
Prud'homme, Robert K. ;
Aksay, Ilhan A. ;
Car, Roberto .
NANO LETTERS, 2008, 8 (01) :36-41
[10]
Measuring thermal conductivity of fluids containing oxide nanoparticles [J].
Lee, S ;
Choi, SUS ;
Li, S ;
Eastman, JA .
JOURNAL OF HEAT TRANSFER-TRANSACTIONS OF THE ASME, 1999, 121 (02) :280-289