Fragmentation of an imido tin(II) cubane; Syntheses and structures of heterobimetallic complexes containing tin(II) imido and phosphinidine anions

被引：42

作者：

Allan, RE ^{[1
]}

Beswick, MA ^{[1
]}

Cromhout, NL ^{[1
]}

Paver, MA ^{[1
]}

Raithby, PR ^{[1
]}

Steiner, A ^{[1
]}

Trevithick, M ^{[1
]}

Wright, DS ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,DEPT CHEM,CAMBRIDGE CB2 1EW,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 13期

关键词：

D O I：

10.1039/cc9960001501

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of the imido tin(II) cubane [SnNBu(t)](4) with 3 equiv. of [C10H7NHLi] (C10H7 = 1-naphthyl) and 6 equiv. of [C6H11PHLi] (C6H11 = cyclohexyl) produce [Li(thf)(4)](+)[(Bu(t)N)(C10H7N)(3)Sn3Li . thf](-). thf . PhMe 1 and [{Sn-2(PC6H11)(3)}Li-2(4) . 4thf]. 2thf 2, respectively, containing the first structurally characterised polyimido and polyphosphinidine anions of a divalent group 14 metal.

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页码：1501 / 1502

页数：2

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