Stability of low-spin ferric hydroperoxo and alkylperoxo complexes with tris(2-pyridylmethyl)amine

被引:17
作者
Lobanova, MV [1 ]
Bryliakov, KP [1 ]
Duban, EA [1 ]
Taksum, EP [1 ]
机构
[1] Russian Acad Sci, GK Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1070/MC2003v013n04ABEH001727
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Quantitative data on the stability and reactivity of the peroxidic intermediates [Fe-III(TPA)(OOH)L](ClO4)(2) and [Fe-III(TPA)-(OOBut)L](ClO4)(2) [TPA=tris(2-pyridylmethyl)amine; L=MeCN, H2O, MeOH and Py] were obtained for the first time.
引用
收藏
页码:175 / 177
页数:3
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