Cp*(iPr3P) Ru(Cl)(η2-HSiClMe2):: the first complex with simultaneous Si-H and RuCl...SiCl inter-ligand interactions

被引：27

作者：

Osipov, AL

Vyboishchikov, SF

Dorogov, KY

Kuzmina, LG

Howard, JAK

Lemenovskii, DA

Nikonov, GI

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia

[2] Univ Girona, Inst Quim Computat, Girona 17071, Catalonia, Spain

[3] RAS, Inst Gen Inorgan Chem, Moscow 119991, Russia

[4] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 26期

关键词：

D O I：

10.1039/b500679a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The addition of HSiMe2Cl to the unsaturated compound Cp*((Pr3P)-Pr-i)RuCl gives an unstable adduct which, according to NMR (J(H-Si) = 33.5 Hz), X-ray crystal structure and DFT evidence, is a silane sigma-complex Cp*((Pr3P)-Pr-i)Ru(Cl)(eta(2)-HSiMe2Cl) supported by an unprecedented, simultaneous inter-ligand (RuClSiCl)-Si-... hypervalent interaction between the chloride ligand on ruthenium and the SiMe2Cl group.

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页码：3349 / 3351

页数：3

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