An efficient synthesis of quaterrylenedicarboximide NIR dyes

被引：29

作者：

Avlasevich, Yuri ^{[1
]}

Muellen, Klaus ^{[1
]}

机构：

[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 26期

关键词：

D O I：

10.1021/jo702019p

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Quaterrylenedicarboximides were prepared from 9-bromoperylene-3,4-dicarboximides by palladium-catalyzed coupling with 3-perylene boronic ester, followed by oxidative cyclo-dehydrogenation of the resulting perylene-perylenedicar-boximide dyads with iron(III) chloride. The quaterrylenedi-carboximides, described here, are highly photochemically and thermally stable dyes, which may be useful as green NIR dyes (lambda(max) = 735 nm) and as building blocks for the synthesis of higher rylene dyes.

引用

页码：10243 / 10246

页数：4

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