An efficient synthesis of quaterrylenedicarboximide NIR dyes

被引:29
作者
Avlasevich, Yuri [1 ]
Muellen, Klaus [1 ]
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
关键词
D O I
10.1021/jo702019p
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Quaterrylenedicarboximides were prepared from 9-bromoperylene-3,4-dicarboximides by palladium-catalyzed coupling with 3-perylene boronic ester, followed by oxidative cyclo-dehydrogenation of the resulting perylene-perylenedicar-boximide dyads with iron(III) chloride. The quaterrylenedi-carboximides, described here, are highly photochemically and thermally stable dyes, which may be useful as green NIR dyes (lambda(max) = 735 nm) and as building blocks for the synthesis of higher rylene dyes.
引用
收藏
页码:10243 / 10246
页数:4
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