Radiolysis of H2O:CO2 ices by heavy energetic cosmic ray analogs

An experimental study of the interaction of heavy, highly charged, and energetic ions (52 MeV Ni-58(13+)) with pure H2O, pure CO2 and mixed H2O:CO2 astrophysical ice analogs is presented. This analysis aims to simulate the chemical and the physicochemical interactions induced by heavy cosmic rays inside dense and cold astrophysical environments, such as molecular clouds or protostellar clouds. The measurements were performed at the heavy ion accelerator GANIL (Grand Accelerateur National d'Ions Lourds in Caen, France). The gas samples were deposited onto a CsI substrate at 13 K. In-situ analysis was performed by a Fourier transform infrared (FTIR) spectrometer at different fluences. Radiolysis yields of the produced species were quantified. The dissociation cross sections of pure H2O and CO2 ices are 1.1 and 1.9 x 10(-13) cm(2), respectively. For mixed H2O: CO2 (10:1), the dissociation cross sections of both species are about 1 x 10(-13) cm(2). The measured sputtering yield of pure CO2 ice is 2.2 x 10(4) molec ion(-1). After a fluence of 2-3 x 10(12) ions cm(-2), the CO2/CO ratio becomes roughly constant (similar to 0.1), independent of the initial CO2/H2O ratio. A similar behavior is observed for the H2O2/H2O ratio, which stabilizes at 0.01, independent of the initial H2O column density or relative abundance.