Synthetic analogues of the active sites of iron-sulfur proteins

被引：498

作者：

Rao, PV ^{[1
]}

Holm, RH ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem & Chem Biol, Cambridge, MA 02138 USA

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 02期

关键词：

D O I：

10.1021/cr020615+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthetic analogues of the active sites in iron-sulfur proteins were studied. X-ray crystallography was used to study the structures. Electron configurations, magnetic ground states and kinetic liability to substitution of terminal ligands were also studied. It was found that all the properties can be attributed to the weak-field nature of the complexes and the clusters.

引用

页码：527 / 559

页数：33

共 353 条

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