Experimental studies of shock-induced ignition and transition to detonation in ethylene and propane mixtures

被引:121
作者
Brown, CJ [1 ]
Thomas, GO [1 ]
机构
[1] Univ Wales, Dept Phys, Aberystwyth SY23 3BZ, Dyfed, Wales
基金
英国工程与自然科学研究理事会;
关键词
D O I
10.1016/S0010-2180(98)00133-3
中图分类号
O414.1 [热力学];
学科分类号
摘要
Results are presented of ignition delay measurements, over the temperature range 1073-2211 K, obtained by monitoring CH emission from ethylene and propane mixtures. The relative influence of argon and nitrogen as diluents is also investigated. Comparisons with other experimental data are made and the validity of chemical kinetic reaction mechanisms discussed. Spark schlieren photographs of the reflection and subsequent ignition processes are also presented, and the effects of varying the diluent and degree of dilution away from ideal conditions investigated. In some cases, acceleration of the reaction wave has been observed, with transition to detonation occurring a short time later. (C) 1999 by The Combustion Institute.
引用
收藏
页码:861 / 870
页数:10
相关论文
共 56 条
[11]   KINETIC MODELING OF ETHYLENE OXIDATION [J].
DAGAUT, P ;
CATHONNET, M ;
BOETTNER, JC ;
GAILLARD, F .
COMBUSTION AND FLAME, 1988, 71 (03) :295-312
[12]   KINETIC MODELING OF PROPANE OXIDATION AND PYROLYSIS [J].
DAGAUT, P ;
CATHONNET, M ;
BOETTNER, JC .
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1992, 24 (09) :813-837
[13]  
DAGAUT P, 1996, COMMUNICATION
[14]   Self-ignition of SI engine model fuels: A shock tube investigation at high pressure [J].
Fieweger, K ;
Blumenthal, R ;
Adomeit, G .
COMBUSTION AND FLAME, 1997, 109 (04) :599-619
[15]  
FIEWEGER K, 1994, 25 S INT COMB COMB I, P1579
[16]   ETHYLENE-OXYGEN REACTION IN SHOCK WAVES [J].
GAY, ID ;
GLASS, GP ;
KERN, RD ;
KISTIAKOWSKY, GB .
JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (01) :313-+
[17]   SHOCK-TUBE STUDY OF IGNITION DELAY TIMES IN METHANE-OXYGEN-NITROGEN-ARGON MIXTURES [J].
GRILLO, A ;
SLACK, MW .
COMBUSTION AND FLAME, 1976, 27 (03) :377-381
[18]   SHOCK-TUBE INVESTIGATION OF IGNITION IN ETHYLENE-OXYGEN-ARGON MIXTURES [J].
HIDAKA, Y ;
KATAOKA, T ;
SUGA, M .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1974, 47 (09) :2166-2170
[19]  
Hillier R., 1991, Shock Waves, V1, P89, DOI 10.1007/BF01414904
[20]  
HILLIER R, 1993, P 19 INT S SHOCK WAV, V4, P17