Combining Metallasupramolecular Chemistry with Dynamic Covalent Chemistry: Synthesis of Large Molecular Cages

被引：83

作者：

Granzhan, Anton ^{[1
]}

Riis-Johannessen, Thomas ^{[1
]}

Scopelliti, Rosario ^{[1
]}

Severin, Kay ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 32期

基金：

瑞士国家科学基金会;

关键词：

cage compounds; dynamic covalent chemistry; macrocycles; ruthenium; self-assembly; TEMPLATE-DIRECTED SYNTHESIS; SUPRAMOLECULAR CHEMISTRY; COMBINATORIAL CHEMISTRY; MACROCYCLES; IONS; RECEPTORS; CAPSULES; HOSTS;

D O I：

10.1002/anie.201002748

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Ru-built cube: By combining metallasupramolecular chemistry with dynamic covalent chemistry, complex nanostructures can be formed. Large cages are synthesized by reaction of trinuclear metallamacrocycles containing pendant aldehyde groups (see picture; Ru blue, aldehyde linkers green) with triamines (red). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5515 / 5518

页数：4

共 52 条

[1]

[Anonymous], 2004, ANGEW CHEM

[2]

[Anonymous], 2008, ANGEW CHEM

[3]

[Anonymous], 2008, ANGEW CHEM

[4] Complex Systems from Simple Building Blocks via Subcomponent Self-Assembly [J].

Campbell, Victoria E. ;

Nitschke, Jonathan R. .

SYNLETT, 2008, (20) :3077-3090

[5] Molecular Borromean rings [J].

Chichak, KS ;

Cantrill, SJ ;

Pease, AR ;

Chiu, SH ;

Cave, GWV ;

Atwood, JL ;

Stoddart, JF .

SCIENCE, 2004, 304 (5675) :1308-1312

[6]

Christinat N., 2008, ANGEW CHEM, V120, P1874

[7] Multicomponent assembly of boronic acid based macrocycles and cages [J].

Christinat, Nicolas ;

Scopelliti, Rosario ;

Severin, Kay .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (10) :1848-1852

[8] Dynamic combinatorial chemistry [J].

Corbett, Peter T. ;

Leclaire, Julien ;

Vial, Laurent ;

West, Kevin R. ;

Wietor, Jean-Luc ;

Sanders, Jeremy K. M. ;

Otto, Sijbren .

CHEMICAL REVIEWS, 2006, 106 (09) :3652-3711

[9] Metallo-supramolecular capsules [J].

Dalgarno, Scott J. ;

Power, Nicholas P. ;

Atwood, Jerry L. .

COORDINATION CHEMISTRY REVIEWS, 2008, 252 (8-9) :825-841

[10] Boronic acids in molecular self-assembly [J].

Fujita, Norifumi ;

Shinkai, Seiji ;

James, Tony D. .

CHEMISTRY-AN ASIAN JOURNAL, 2008, 3 (07) :1076-1091

← 1 2 3 4 5 6 →