Combining Metallasupramolecular Chemistry with Dynamic Covalent Chemistry: Synthesis of Large Molecular Cages

被引：83

作者：

Granzhan, Anton ^{[1
]}

Riis-Johannessen, Thomas ^{[1
]}

Scopelliti, Rosario ^{[1
]}

Severin, Kay ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 32期

基金：

瑞士国家科学基金会;

关键词：

cage compounds; dynamic covalent chemistry; macrocycles; ruthenium; self-assembly; TEMPLATE-DIRECTED SYNTHESIS; SUPRAMOLECULAR CHEMISTRY; COMBINATORIAL CHEMISTRY; MACROCYCLES; IONS; RECEPTORS; CAPSULES; HOSTS;

D O I：

10.1002/anie.201002748

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Ru-built cube: By combining metallasupramolecular chemistry with dynamic covalent chemistry, complex nanostructures can be formed. Large cages are synthesized by reaction of trinuclear metallamacrocycles containing pendant aldehyde groups (see picture; Ru blue, aldehyde linkers green) with triamines (red). © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5515 / 5518

页数：4