Oxidation of aromatic aldehydes and ketones by H2O2/CH3ReO3 in ionic liquids:: a catalytic efficient reaction to achieve dihydric phenols

被引:88
作者
Bernini, R
Coratti, A
Provenzano, G
Fabrizi, G
Tofani, D
机构
[1] Univ Tuscia, Dipartimento ABAC, I-01100 Viterbo, Italy
[2] Univ Roma La Sapienza, Dipartimento Studi Chim & Tecnol Sostanze Biologi, I-00185 Rome, Italy
[3] Univ Roma Tre, Dipartimento Ingn Meccan & Ind, I-00146 Rome, Italy
关键词
D O I
10.1016/j.tet.2004.12.025
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A convenient and efficient application of hydrogen peroxide/methyltrioxorhenium in ionic liquids [bmim]BF4 and [bmim]PF6 for the oxidation of hydroxylated and methoxylated benzaldehydes and acetophenones to the corresponding phenols is described. Good yields of products were obtained in short reaction times. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1821 / 1825
页数:5
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