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CH3ReO3/H2O2 in room temperature ionic liquids:: an homogeneous recyclable catalytic system for the Baeyer-Villiger reaction

被引：61
作者：
Bernini, R
Coratti, A
Fabrizi, G
Goggiamani, A
机构：
[1] Univ Tuscia, Dipartimento ABAC, I-01100 Viterbo, Italy
[2] Univ Roma La Sapienza, Dipartimento Chim & Tecnol Sostanze Biologicament, I-00185 Rome, Italy
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 50期
关键词：
Baeyer Villiger reaction; cyclic ketones; lactones; ionic liquids; bmim]BF4-;
D O I：
10.1016/j.tetlet.2003.10.002
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Baeyer-Villiger oxidation of cyclic ketones can be effected by methyltrioxorhenium/hydrogen peroxide in the ionic liquid [bmim]BF4. After simple extraction of the lactone with diethyl ether, the catalyst can be repeatedly recycled and efficiently reused for the lactonisation process in the same reaction medium. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：8991 / 8994
页数：4
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