Catalytic asymmetric dihydroxylation of olefins using a recoverable and reusable OsO42- in ionic liquid [bmim][PF6]

被引:58
作者
Branco, LC [1 ]
Afonso, CAM [1 ]
机构
[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, Dept Quim, REQUIMTE,CQFB, P-2829516 Caparica, Portugal
关键词
D O I
10.1039/b208631j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The use of the solvent systems water/ionic liquid or water/ionic liquid/tert-butanol provides a recoverable, reusable, robust and simple system for the asymmetric dihydroxylation of olefins, based on the immobilization of the osmium-ligand catalyst in the ionic liquid phase.
引用
收藏
页码:3036 / 3037
页数:2
相关论文
共 48 条
  • [1] Sharpless asymmetric dihydroxylation on an industrial scale
    Ahrgren, L
    Sutin, L
    [J]. ORGANIC PROCESS RESEARCH & DEVELOPMENT, 1997, 1 (06) : 425 - 427
  • [2] CO2 capture by a task-specific ionic liquid
    Bates, ED
    Mayton, RD
    Ntai, I
    Davis, JH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (06) : 926 - 927
  • [3] Recovery of organic products from ionic liquids using supercritical carbon dioxide
    Blanchard, LA
    Brennecke, JF
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2001, 40 (01) : 287 - 292
  • [4] Green processing using ionic liquids and CO2
    Blanchard, LA
    Hancu, D
    Beckman, EJ
    Brennecke, JF
    [J]. NATURE, 1999, 399 (6731) : 28 - 29
  • [5] Asymmetric dihydroxylation with MeO-polyethyleneglycol-bound ligands
    Bolm, C
    Gerlach, A
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (07): : 741 - 743
  • [6] Bösmann A, 2001, ANGEW CHEM INT EDIT, V40, P2697, DOI 10.1002/1521-3773(20010716)40:14<2697::AID-ANIE2697>3.0.CO
  • [7] 2-W
  • [8] Branco LC, 2002, CHEM-EUR J, V8, P3671, DOI 10.1002/1521-3765(20020816)8:16<3671::AID-CHEM3671>3.0.CO
  • [9] 2-9
  • [10] Branco LC, 2002, CHEM-EUR J, V8, P3865, DOI 10.1002/1521-3765(20020902)8:17<3865::AID-CHEM3865>3.0.CO