Catalysis for green chemistry

被引：113

作者：

Clark, JH ^{[1
]}

机构：

[1] Univ York, Dept Chem, Clean Technol Ctr, York YO10 5DD, N Yorkshire, England

来源：

PURE AND APPLIED CHEMISTRY | 2001年 / 73卷 / 01期

关键词：

D O I：

10.1351/pac200173010103

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of heterogenization as a method for achieving clean synthesis is discussed. The chemical modification of mesoporous solids can be used to make a range of catalysts, including solid acids and bases, and stable metal complexes for selective oxidations and other reactions. By avoiding an aqueous quench stage in the separation, the heterogenization of catalysts and reagents carl lead to substantial reductions in waste produced in organic chemical manufacturing processes.

引用

页码：103 / 111

页数：9

共 17 条

[1]

Clark J.H., 2000, RSC CLEAN TECHNOL MO

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Clark, JH ;

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[4]

*CONTR CAT, ENV

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CHEMICAL COMMUNICATIONS, 2000, (07) :605-606

[6] Preparation of a silica-supported peroxycarboxylic acid and its use in the epoxidation of alkenes [J].

Elings, JA ;

Ait-Meddour, R ;

Clark, JH ;

Macquarrie, DJ .

CHEMICAL COMMUNICATIONS, 1998, (24) :2707-2708

[7]

GRIGOROPOULOU G, 2001, IN PRESS CHEM COMM

[8] Chemistry on the inside: green chemistry in mesoporous materials [J].

Macquarrie, DJ .

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2000, 358 (1766) :419-430

[9] Direct syntheses of ordered SBA-15 mesoporous silica containing sulfonic acid groups [J].

Margolese, D ;

Melero, JA ;

Christiansen, SC ;

Chmelka, BF ;

Stucky, GD .

CHEMISTRY OF MATERIALS, 2000, 12 (08) :2448-2459

[10] Modified silicas for clean technology [J].

Price, PM ;

Clark, JH ;

Macquarrie, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (02) :101-110

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