A sandwich complex of lithium oxide:: {Li[BunC(NBut)2]}4•Li2O

被引:47
作者
Chivers, T [1 ]
Downard, A
Yap, GPA
机构
[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada
[2] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 16期
关键词
D O I
10.1039/a804955f
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Hydrolysis of {Li[(BuC)-C-n(NBut)(2)]}(2), prepared from LiBun and (BuNCNBut)-N-t in hexanes, produced the nineteen atom cluster {Li[(BuC)-C-n(NBut)(2)]}4 . Li2O; an X-ray structure determination revealed an Li2O molecule encapsulated by two eight-membered Li2N4C2 rings.
引用
收藏
页码:2603 / 2605
页数:3
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