Size-dependent spintronic properties of dilute magnetic semiconductor nanocrystals

被引:102
作者
Huang, XY [1 ]
Makmal, A
Chelikowsky, JR
Kronik, L
机构
[1] Univ Minnesota, Dept Chem Engn & Mat Sci, Inst Theory Adv Mat Informat Technol, Digital Technol Ctr, Minneapolis, MN 55455 USA
[2] Weizmann Inst Sci, Dept Mat & Interfaces, IL-76100 Rehovot, Israel
关键词
D O I
10.1103/PhysRevLett.94.236801
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The electronic structure and magnetic properties of Mn-doped Ge, GaAs, and ZnSe nanocrystals are investigated using real space ab initio pseudopotentials constructed within the local spin-density approximation. The ferromagnetic and half-metallicity trends found in the bulk are preserved in the nanocrystals. However, the Mn-related impurity states become much deeper in energy with decreasing nanocrystalline size, causing the ferromagnetic stabilization to be dominated by double exchange via localized holes rather than by a Zener-like mechanism.
引用
收藏
页数:4
相关论文
共 32 条
[1]  
BANYAI L, 1993, SEMICONDUCTOR QUANTU
[2]  
Blundell S., 2014, Magnetism in Condensed Matter
[3]   FINITE-DIFFERENCE-PSEUDOPOTENTIAL METHOD - ELECTRONIC-STRUCTURE CALCULATIONS WITHOUT A BASIS [J].
CHELIKOWSKY, JR ;
TROULLIER, N ;
SAAD, Y .
PHYSICAL REVIEW LETTERS, 1994, 72 (08) :1240-1243
[4]   Time-dependent density-functional calculations for the optical spectra of molecules, clusters, and nanocrystals [J].
Chelikowsky, JR ;
Kronik, L ;
Vasiliev, I .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (35) :R1517-R1547
[5]   Ferromagnetism in Mn-doped Ge [J].
Cho, SG ;
Choi, S ;
Hong, SC ;
Kim, Y ;
Ketterson, JB ;
Kim, BJ ;
Kim, YC ;
Jung, JH .
PHYSICAL REVIEW B, 2002, 66 (03) :333031-333033
[6]   Zener model description of ferromagnetism in zinc-blende magnetic semiconductors [J].
Dietl, T ;
Ohno, H ;
Matsukura, F ;
Cibert, J ;
Ferrand, D .
SCIENCE, 2000, 287 (5455) :1019-1022
[7]   The electronic structure of semiconductor nanocrystals [J].
Efros, AL ;
Rosen, M .
ANNUAL REVIEW OF MATERIALS SCIENCE, 2000, 30 :475-521
[8]   Carrier-induced ferromagnetism in p-Zn1-xMnxTe -: art. no. 085201 [J].
Ferrand, D ;
Cibert, J ;
Wasiela, A ;
Bourgognon, C ;
Tatarenko, S ;
Fishman, G ;
Andrearczyk, T ;
Jaroszynski, J ;
Kolesnik, S ;
Dietl, T ;
Barbara, B ;
Dufeu, D .
PHYSICAL REVIEW B, 2001, 63 (08)
[9]   Prospects for carrier-mediated ferromagnetism in GaN [J].
Graf, T ;
Goennenwein, STB ;
Brandt, MS .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 2003, 239 (02) :277-290
[10]   Observation of a ferromagnetic transition induced by two-dimensional hole gas in modulation-doped CdMnTe quantum wells [J].
Haury, A ;
Wasiela, A ;
Arnoult, A ;
Cibert, J ;
Tatarenko, S ;
Dietl, T ;
dAubigne, YM .
PHYSICAL REVIEW LETTERS, 1997, 79 (03) :511-514