Stable germanium analogs of carbenes, imines, ketones, thiones, selones and tellones

被引:185
作者
Barrau, J [1 ]
Rima, G [1 ]
机构
[1] Univ Toulouse 3, UPRES A 5069, CNRS, Lab Heterochim Fondamentale & Appl, F-31062 Toulouse 4, France
关键词
germanium compounds; stable germylenes;
D O I
10.1016/S0010-8545(98)00076-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The chemistry of low coordinate germanium compounds has made important advances in recent years and a rather large number of these species have been isolated in a monomeric state owing to both electronic and/or steric effects. This review reports with their synthetic routes the stable germylenes drop Ge and the stable germanimines, germanone, germanethiones, -selones and -tellones drop Ge=Y (Y=N-, O, S, Se, Te) prepared up to now, focusing particularly on compounds whose structures have been determined. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:593 / 622
页数:30
相关论文
共 117 条
  • [1] The role of the 2,4,6-tris(trifluoromethyl)phenylamino group in stabilizing new phosphorus-, arsenic-, and germanium-containing main-group compounds and transition-metal derivatives
    Ahlemann, JT
    Roesky, HW
    Murugavel, R
    Parisini, E
    Noltemeyer, M
    Schmidt, HG
    Muller, O
    HerbstIrmer, R
    Markovskii, LN
    Shermolovich, YG
    [J]. CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (08): : 1113 - 1121
  • [2] ELECTRONIC ABSORPTION-SPECTRA OF DIORGANOGERMYLENES IN MATRICES - FORMATION OF DIORGANOGERMYLENE COMPLEXES WITH HETEROATOM-CONTAINING SUBSTRATES
    ANDO, W
    ITOH, H
    TSUMURAYA, T
    [J]. ORGANOMETALLICS, 1989, 8 (12) : 2759 - 2766
  • [3] SYNTHESIS, STRUCTURE, AND PHOTOREACTION OF BIS(GERMANIMINES)
    ANDO, W
    OHTAKI, T
    KABE, Y
    [J]. ORGANOMETALLICS, 1994, 13 (02) : 434 - 435
  • [4] METALLA IVB-PHOSPHOLANNES .1. DIMETALLA-2,5 PHOSPHOLANNES, METALLA-2 DIPHOSPHOLANNES-1,3 ET METALLA-3 DIPHOSPHOLANNES-1,2
    ANDRIAMIZAKA, JD
    COURET, C
    ESCUDIE, J
    SATGE, J
    [J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1982, 12 (03): : 265 - 278
  • [5] A NOVEL SYNTHESIS AND PROPERTIES OF N-TRIFLUOROMETHYLGERMAIMINE, CF3N=GEH2
    ANG, HG
    LEE, FK
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (05) : 310 - 311
  • [6] ANG HG, 1989, FLUORINE CHEM, V43, P345
  • [7] MACROCYCLIC (C22H22N4) COMPLEXES OF GERMANIUM(II), TIN(II), GALLIUM(III), AND INDIUM(III) - MAIN GROUP FUNCTIONALITIES IN UNUSUAL ENVIRONMENTS
    ATWOOD, DA
    ATWOOD, VO
    COWLEY, AH
    ATWOOD, JL
    ROMAN, E
    [J]. INORGANIC CHEMISTRY, 1992, 31 (19) : 3871 - 3872
  • [8] Baines K. M., 1996, ADV ORGANOMET CHEM, V39, P275, DOI DOI 10.1016/S0065-3055(08)60470-0
  • [9] MULTIPLY BONDED GERMANIUM SPECIES - RECENT DEVELOPMENTS
    BARRAU, J
    ESCUDIE, J
    SATGE, J
    [J]. CHEMICAL REVIEWS, 1990, 90 (01) : 283 - 319
  • [10] New bivalent germanium, tin and lead compounds with M-O bond
    Barrau, J
    Rima, G
    ElAmraoui, T
    [J]. INORGANICA CHIMICA ACTA, 1996, 241 (02) : 9 - 10