Layered manganites: Magnetic structure at extreme doping levels

被引:30
作者
Mitchell, JF [1 ]
Millburn, JE [1 ]
Medarde, M [1 ]
Argyriou, DN [1 ]
Jorgensen, JD [1 ]
机构
[1] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
关键词
D O I
10.1063/1.370498
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report powder neutron diffraction results on the crystal and magnetic structures of the bilayer Ruddlesden-Popper phase Sr3Mn2O7-delta(delta = 0.0, 0.45) and correlate these structures with their magnetic and transport properties. The delta = 0.45 compound contains a large number of oxygen vacancies that are disordered in the MnO2 planes. As a result of this disordered vacancy structure, Sr3Mn2O6.55 is a nonmagnetic insulator. Sr3Mn2O7.0(delta = 0) is an antiferromagnetic insulator whose magnetic structure is related to that of the SrMnO3 perovskite. Comparison of this end-member compound to its doped congeners in the La2-2xSr1+2xMn2O7 series highlights the extreme sensitivity of magnetic structure to dopant concentration in these layered materials. (C) 1999 American Institute of Physics. [S0021-8979(99)18608-0].
引用
收藏
页码:4352 / 4354
页数:3
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