Transformation of β-Ni(OH)2 to NiO nano-sheets via surface nanocrystalline zirconia coating:: Shape and size retention

被引:14
作者
Cheng, Ming-Yao [2 ]
Hwang, Bing-Joe [1 ,2 ]
机构
[1] Natl Synchrotron Radiat Res Ctr, Hsinchu 300, Taiwan
[2] Natl Taiwan Univ, Dept Chem Engn, Nanoelectrochem Lab, Taipei 106, Taiwan
来源
NANOSCALE RESEARCH LETTERS | 2007年 / 2卷 / 01期
关键词
thermal stability; nickel oxide; solid oxide fuel cell; surface coating; anode;
D O I
10.1007/s11671-006-9025-5
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Shape and size of the synthesized NiO nano-sheets were retained during transformation of sheet-like beta-Ni(OH)(2) to NiO at elevated temperatures via nano-sized zirconia coating on the surface of beta b-Ni(OH)(2). The average grain size was 6.42 nm after 600 degrees C treatment and slightly increased to 10 nm after 1000 degrees C treatment, showing effective sintering retardation between NiO nano-sheets. The excellent thermal stability revealed potential application at elevated temperatures, especially for high temperature catalysts and solid-state electrochemical devices.
引用
收藏
页码:28 / 33
页数:6
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