Ruthenium-catalyzed allylic substitution of allylic cyclic carbonates

被引：19

作者：

Kang, SK

Kim, DY

Hong, RK

Ho, PS

机构：

[1] Department of Chemistry, Sung Kyun Kwan University, Natural Science Campus

来源：

SYNTHETIC COMMUNICATIONS | 1996年 / 26卷 / 17期

关键词：

D O I：

10.1080/00397919608004631

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allylic substitution of allylic cyclic carbonates with PhSH or PhOH in the presence of CpRu(PPh(3))(2)Cl (5 mol %) afforded (E)-allylic alcohol and erythro-beta-hydroxy thiophenoxide or phenoxide respectively, via external attack of nucleophiles to x-allyl ruthenium complex.

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页码：3225 / 3235

页数：11

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