Optimizing the solar photo-Fenton process in the treatment of contaminated water. Determination of intrinsic kinetic constants for scale-up

被引：85

作者：

Rodríguez, M

Malato, S

Pulgarin, C

Contreras, S

Curcó, D

Giménez, J

Esplugas, S

机构：

[1] Univ Barcelona, Dept Engn Quim & Met, E-08028 Barcelona, Spain

[2] Univ Los Andes, Escuela Bas Ingn, Merida, Venezuela

[3] Ecole Polytech Fed Lausanne, Swiss Fed Inst Technol, Inst Environm Engn, Lab Environm Biotechnol, CH-1015 Lausanne, Switzerland

[4] PSA, Tabernas, Spain

来源：

SOLAR ENERGY | 2005年 / 79卷 / 04期

关键词：

photocatalysis; solar radiation; hydrogen peroxide; iron salts; photo-fenton; DEGRADATION;

D O I：

10.1016/j.solener.2005.02.024

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

080707 [能源环境工程]; 082001 [油气井工程];

摘要：

The elimination of aromatic compounds present in surface water by photo-Fenton with sunlight as the source of radiation was studied. The concentrations of Fe3+ and H2O2 are key factors for this process. A solar simulator and a prototype parabolic collector were used as laboratory-scale reactors to find the parameters of those key factors to be used in the CPC (compound parabolic collector) pilot plant reactor. The initial mineralization rate constant (k(obs)) was determined and evaluated at different Fe3+ and H2O2 concentrations to find the best values for maximum efficiency. In all the experiments the mineralization of an aqueous phenol solution was described by assuming a pseudo-first-order reaction. The intrinsic kinetic constants not dependent on the lighting conditions were also estimated for scale-up. (c) 2005 Elsevier Ltd. All rights reserved.

引用

页码：360 / 368

页数：9

共 23 条

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Effects of ozonation on the biodegradability of substituted phenols [J].