Azacrownlactams derived from biphenyl.: Study of their conformations, complexation ability and electrochemical behavior

被引：9

作者：

Costero, AM

Aurell, MJ

Bañuls, MJ

Ochando, LE

Tamarit, FJ

Domenech, A

机构：

[1] Univ Valencia, Dept Quim Organ, Fac Quim, E-46100 Valencia, Spain

[2] Univ Valencia, Dept Geol, Fac Quim, E-46100 Valencia, Spain

[3] Univ Valencia, Dept Quim Analit, Fac Quim, E-46100 Valencia, Spain

来源：

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2003年 / 45卷 / 3-4期

关键词：

azacrownlactams; biphenyl; complexation; electrochemistry;

D O I：

10.1023/A:1024510417063

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Several macrolactams containing in their structure biphenyl and pyridine moieties have been synthesized. The complexation ability of these compounds has been evaluated and the results have been explained considering the existence of intramolecular hydrogen bonds. Conformational studies have been developed in some cases. Single-crystal X-ray diffraction studies have been carried out with one of the ligands. The electrochemical response of ligands 1 and 3 has been studied using cyclic and square wave voltammetry. The interaction of these ligands with Cu2+ ions in CH3CN has been investigated by electrochemical techniques.

引用

页码：241 / 249

页数：9