Structure of a benzylcalcium diastereomer: An initiator for the anionic polymerization of styrene

被引：129

作者：

Harder, S ^{[1
]}

Feil, F ^{[1
]}

Weeber, A ^{[1
]}

机构：

[1] Univ Konstanz, D-78457 Constance, Germany

来源：

ORGANOMETALLICS | 2001年 / 20卷 / 06期

关键词：

D O I：

10.1021/om000945p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new dibenzylcalcium compound with chiral anionic centers has been prepared and was structurally characterized. The compound, which shows slow inversion of the chiral carbanions, is an active,initiator for the living polymerization of styrene.

引用

页码：1044 / 1046

页数：3

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