Formation and reactivity of a peroxide adduct of iron(III) complexes containing substituted phenol derivatives

被引:34
作者
Ito, S
Suzuki, M
Kobayashi, T
Itoh, H
Harada, A
Ohba, S
Nishida, Y
机构
[1] YAMAGATA UNIV,FAC SCI,DEPT CHEM,YAMAGATA 990,JAPAN
[2] KEIO UNIV,FAC SCI & TECHNOL,DEPT CHEM,YOKOHAMA,KANAGAWA 223,JAPAN
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 12期
关键词
D O I
10.1039/dt9960002579
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Binding of the oxygen atom of iron(III)-peroxide adducts to phenol rings has been found to be highly controlled by the substituents on the ring, implying that the interaction between the adduct and the ring involves an electronic attractive force, whereby the adduct acts as an electrophile.
引用
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页码:2579 / 2580
页数:2
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