The compound [Ti4O4{OCH2CH2N(CH3)2}8] containing the new Ti4O4 cluster core

被引:23
作者
Johnson, BFG
Klunduk, MC
O'Connell, TJ
McIntosh, C
Ridland, J
机构
[1] Univ Cambridge, Chem Lab, Cambridge CB2 1EW, England
[2] Synetix, Billingham TS23 1LB, Cleveland, England
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 10期
关键词
D O I
10.1039/b102099o
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of [Ti(OPri)(4)] with the bidentate ligand (CH3)(2)NCH2CH2O- (DMEA) followed by controlled hydrolysis yields the new tetranuclear compound [Ti4O4(DMEA)(8)] involving a novel Ti4O4 central core and three different bonding modes of the DMEA ligand.
引用
收藏
页码:1553 / 1555
页数:3
相关论文
共 52 条
[1]  
ASLAN H, 1986, J ORGANOMET CHEM, V69, P315
[2]   SYNTHESIS AND STRUCTURE OF AN ORGANOTITANOXANE CONTAINING A TETRAHEDRAL TI4O6 CAGE, [(ETA-5-C5ME5)TI]4O6 [J].
BABCOCK, LM ;
DAY, VW ;
KLEMPERER, WG .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (11) :858-859
[3]   Preparation and x-ray crystallographic characterisation of the trititanate [Ti3O(mu-OPr(i))(3)(OPr(i))(4){Me2C(O)CH=C(O)CH2C(O)Me-2}], a reaction product of [Ti(OPri)(4)] and propan-2-one [J].
Barkley, JV ;
Cannadine, JC ;
Hannaford, I ;
Harding, MM ;
Steiner, A ;
Tallon, J ;
Whyman, R .
CHEMICAL COMMUNICATIONS, 1997, (17) :1653-1654
[4]   Preparation and characterization of (C5Me4Ph)TiCl3, the oxochloride complexes [(C5Me4Ph)TiCl2](2)(mu-O) and [(C5Me4Ph)TiCl(mu-O)](3) and the oxo-complex [(C5Me4Ph)Ti](4)(mu-O)(6). The X-ray crystal structures of [(C5Me4Ph)TiCl2](2)(mu-O) and [(C5Me4Ph)Ti](4)(mu-O)(6) [J].
Bjorgvinsson, M ;
Halldorsson, S ;
Arnason, I ;
Magull, J ;
Fenske, D .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 544 (02) :207-215
[5]   SYNTHETIC, STRUCTURAL, AND PHYSICAL STUDIES OF TITANIUM COMPLEXES OF CATECHOL AND 3,5-DI-TERT-BUTYLCATECHOL [J].
BORGIAS, BA ;
COOPER, SR ;
KOH, YB ;
RAYMOND, KN .
INORGANIC CHEMISTRY, 1984, 23 (08) :1009-1016
[6]   Formic acid modified Ti(OCHMe2)4.: Syntheses, characterization, and X-ray structures of Ti4(μ4-O)(μ-O)(OFc)2(μ-OR)4(OR)6 and Ti6(μ3-O)6(OFc)6(OR)6 (OFc = O2CH; OR = OCHMe2) [J].
Boyle, TJ ;
Alam, TM ;
Tafoya, CJ ;
Scott, BL .
INORGANIC CHEMISTRY, 1998, 37 (21) :5588-5594
[7]   Polyoxotitanates join the Keggin family: Synthesis, structure and reactivity of [Ti18O28H][OBu(t)](17) [J].
Campana, CF ;
Chen, Y ;
Day, VW ;
Klemperer, WG ;
Sparks, RA .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (05) :691-702
[8]   MONOCYCLOPENTADIENYLCHLOROOXOTITANIUM(IV) DIMERS, TRIMERS AND TETRAMERS [J].
CAROFIGLIO, T ;
FLORIANI, C ;
SGAMELLOTTI, A ;
ROSI, M ;
CHIESIVILLA, A ;
RIZZOLI, C .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1992, (06) :1081-1087
[9]   A NOVEL CLASS OF HEXANUCLEAR TITANOXANES - SYNTHESIS, STRUCTURE AND ELECTRONIC CONFIGURATION [J].
CAROFIGLIO, T ;
FLORIANI, C ;
ROTH, A ;
SGAMELLOTTI, A ;
ROSI, M ;
CHIESIVILLA, A ;
RIZZOLI, C .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 488 (1-2) :141-154
[10]  
CHEN YW, 1992, MATER RES SOC SYMP P, V271, P57, DOI 10.1557/PROC-271-57