Synthesis and structure of {[Gd(OSO)(3)(mu-F2AsF4)(6/2)]center dot 0.25SO(2)}(m)

被引：15

作者：

Petersen, J

Lork, E

Mews, R

机构：

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 22期

关键词：

D O I：

10.1039/cc9960002593

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidation of lanthanide metals with AsF5 in liquid SO2 yields the corresponding polymeric {[M(SO2)(n)](AsF6)(3)}(m) (1a-j, M = Y, La, Ce, Pr, Nd, Sm, Gd, Dy, Er, Yb) where the metal centres are bridged by AsF6 units; the X-ray crystal structure of the Gd complex 1g is reported.

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页码：2593 / 2594

页数：2

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