(η6-Arene)tricarbonylchromium and (η5-cyclohexadienyl)tricarbonylmanganese complexes:: indirect nucleophilic substitutions

被引：73

作者：

Rose-Munch, F ^{[1
]}

Gagliardini, V ^{[1
]}

Renard, C ^{[1
]}

Rose, E ^{[1
]}

机构：

[1] Univ Paris 06, UMR CNRS 761 1, Lab Synthese Organ & Organomet, F-75252 Paris 05, France

来源：

COORDINATION CHEMISTRY REVIEWS | 1998年 / 178卷

关键词：

arene; arene complexes; aromatic substitution; benzenetricarbonylchromium; benzenetricarbonylmanganese; nucleophilic substitution;

D O I：

10.1016/S0010-8545(98)00078-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of X-substituted (eta(6)-arene) tricarbonylchromium complexes with a nucleophile and a proton source afforded new arenetricarbonylchromium complexes via chromium hydride intermediates and elimination of HX (cine and tele nucleophilic aromatic substitutions). Treatment of (eta(5)-X-substituted-cyclohexadienyl)tricarbonyl manganese complexes with hydride and a proton source gave eta(5)-cyclohexadienyl complexes resulting from a cleavage of the C-X bond: the eta(3)-X-substituted cyclohexenyl intermediates underwent elimination of an agostic hydrogen and the X group. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：249 / 268

页数：20

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