A transition metal complex containing pyrazine-2,5-dicarboxylato bridging ligands:: a novel three-dimensional manganese(II) compound

被引：18

作者：

Beobide, G ^{[1
]}

Castillo, O ^{[1
]}

Luque, A ^{[1
]}

García-Couceiro, U ^{[1
]}

García-Teran, JP ^{[1
]}

Román, P ^{[1
]}

Lezama, L ^{[1
]}

机构：

[1] Univ Basque Country, Dept Quim Inorgan, E-48080 Bilbao, Spain

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 09期

关键词：

pyrazine bridge; three-dimensional complex; manganese complex; dicarboxylate; crystal structure; magnetic properties;

D O I：

10.1016/S1387-7003(03)00237-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel metal-organic polymer [Mn(mu(4)-pzdc)](n) (H(2)pzdc = pyrazine-2,5-dicarboxylic acid) has been synthesized by the hydrothermal reaction of Mn(NO3)(2).4H(2)O with H(2)Pzdc. X-ray diffraction analysis shows that the polymer exhibits an extended three-dimensional network with hexadentated pzdc ligands bridging four manganese(II) atoms. The magnetic measurements show the occurrence of weak antiferromagnetic couplings. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：1224 / 1227

页数：4

共 37 条

[1] X-ray powder structure of a new two-dimensional nickel(II) coordination polymer with pyrazine-2,3,5,6-tetracarboxylic acid [J].

Alfonso, M ;

Neels, A ;

Stoeckli-Evans, H .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2001, 57 (10) :1144-1146

[2]

Barthelet K, 2002, ANGEW CHEM INT EDIT, V41, P281, DOI 10.1002/1521-3773(20020118)41:2<281::AID-ANIE281>3.0.CO

[3]

2-Y

[4] A new CuI(SCN) structural motif:: synthesis of an uncharged three-dimensional co-ordination network [J].

Blake, AJ ;

Champness, NR ;

Crew, M ;

Hanton, LR ;

Parsons, S ;

Schroder, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (10) :1533-1534

[5] 2,2'-BIPYRIMIDINE-BRIDGED HOMOBINUCLEAR COMPLEXES [J].

BREWER, G ;

SINN, E .

INORGANIC CHEMISTRY, 1985, 24 (26) :4580-4584

[6]

BROWN SB, 1979, INORG CHIM ACTA, V34, P221

[7] Syntheses, crystal structures, and magnetic properties of one-dimensional oxalato-bridged Co(II), Ni(II), and Cu(II) complexes with n-aminopyridine (n=2-4) as terminal ligand [J].

Castillo, O ;

Luque, A ;

Román, P ;

Lloret, F ;

Julve, M .

INORGANIC CHEMISTRY, 2001, 40 (22) :5526-5535

[8] Layered metal organosulfides:: hydrothermal synthesis, structure and magnetic behaviour of the spin-canted magnet Co(1,2-(O2C)(S)C6H4) [J].

Cave, D ;

Gascon, JM ;

Bond, AD ;

Teat, SJ ;

Wood, PT .

CHEMICAL COMMUNICATIONS, 2002, (10) :1050-1051

[9] Architecture dependence on the steric constrains of the ligand in cyano-bridged copper(I) and Copper(II)-Copper(I) mixed-valence polymer compounds containing diamines:: Crystal structures and spectroscopic and magnetic properties [J].

Colacio, E ;

Kivekas, R ;

Lloret, F ;

Sunberg, M ;

Suarez-Varela, J ;

Bardají, M ;

Laguna, A .

INORGANIC CHEMISTRY, 2002, 41 (20) :5141-5149

[10] Synthesis, structure, and fluorescence of the novel cadmium(II)-trimesate coordination polymers with different coordination architectures [J].

Dai, JC ;

Wu, XT ;

Fu, ZY ;

Cui, CP ;

Hu, SM ;

Du, WX ;

Wu, LM ;

Zhang, HH ;

Sun, RO .

INORGANIC CHEMISTRY, 2002, 41 (06) :1391-1396

← 1 2 3 4 →