Unusual Chain-Length Dependence of the Diffusion of n-Alkanes in the Metal-Organic Framework MIL-47(V): The Blowgun Effect

被引：43

作者：

Jobic, Herve ^{[1
]}

Rosenbach, Nilton, Jr. ^{[2
]}

Ghoufi, Aziz ^{[3
]}

Kolokolov, Daniil I. ^{[1
]}

Yot, Pascal G. ^{[2
]}

Devic, Thomas ^{[4
]}

Serre, Christian ^{[4
]}

Ferey, Gerard ^{[4
]}

Maurin, Guillaume ^{[2
]}

机构：

[1] Univ Lyon, CNRS, Inst Rech Catalyse & Environm Lyon, F-69626 Villeurbanne, France

[2] Univ Montpellier 2, CNRS, Inst Charles Gerhardt Montpellier, UMR 5253, F-34095 Montpellier 05, France

[3] Univ Rennes 1, CNRS, Inst Phys Rennes, UMR 6251, F-35042 Rennes, France

[4] Univ Versailles, CNRS, Inst Lavoisier, UMR 8180, F-78035 Versailles, France

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 34期

关键词：

alkanes; blowgun effect; diffusion; metal-organic frameworks; molecular dynamics; neutron scattering; ELASTIC NEUTRON-SCATTERING; SHORT LINEAR ALKANES; MOLECULAR-DYNAMICS; TRANSPORT DIFFUSIVITY; ADSORPTION; SIMULATION; MIXTURES; MICROCALORIMETRY; HYDROCARBONS; COMBINATION;

D O I：

10.1002/chem.201001521

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hootie and the blowgun effect: Quasielastic neutron scattering experiments and MD simulations have been coupled to deepen our understanding of the diffusion mechanism for shortlength alkanes in the MIL-47(V) MOF-type material. All alkanes follow a 1D-type diffusion, while a spectacular blowgun-type diffusion has been evidenced for n-butane from a higher diffusivity at low loading of this alkane compared with propane. (Figure Presented) © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10337 / 10341

页数：5

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