An amino-modified Zr-terephthalate metal-organic framework as an acid-base catalyst for cross-aldol condensation

被引：379

作者：

Vermoortele, Frederik ^{[1
]}

Ameloot, Rob ^{[1
]}

Vimont, Alexandre ^{[2
]}

Serre, Christian ^{[3
]}

De Vos, Dirk ^{[1
]}

机构：

[1] Katholieke Univ Leuven, Dept Microbial & Mol Syst, Ctr Surface Chem & Catalysis, B-3001 Heverlee, Belgium

[2] ENSICAEN, CNRS, UMR 6506, Catalyse & Spectrochim Lab, F-14050 Caen, France

[3] Univ Versailles St Quentin En Yvelines, CNRS, UMR 8180, Inst Lavoisier, F-78035 Versailles, France

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 05期

关键词：

FINE CHEMICALS; CARBOXYLATE; INFILTRATION; STABILITY; MOF-5;

D O I：

10.1039/c0cc03038d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

After controlled pretreatment, some Zr-terephthalate metal-organic frameworks are highly selective catalysts for the cross-aldol condensation between benzaldehyde and heptanal. The proximity of Lewis acid and base sites in the amino-functionalized UiO-66(NH2) material further raises the reaction yields.

引用

页码：1521 / 1523

页数：3

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